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thermodynamics GATE
THERMODYNAMICS
Yes — the confusing part is why . Let's go through that step very slowly.
We started with:
So
Step 1: Integrate with respect to
We want to find . Since
we integrate:
Therefore,
Here is treated as a constant, because we're integrating with respect to .
So:
and
Thus:
Why ?
This is the important bit.
When you integrate with respect to , you can have any function of as the "constant."
For example:
The disappears because we're differentiating with respect to .
So we don't know yet what that function is. We call it:
Step 2: Differentiate this with respect to
Now:
Differentiate with respect to :
Therefore:
so:
Step 3: Now use the information we already have
From our original differential:
we know that the coefficient of is
But by definition,
Therefore:
Subtract from both sides:
And if
then must simply be a constant:
Hence:
The key idea
Think of it like this:
That's why we initially write
rather than simply .
Then the second piece of information, , tells us what must be.
And this is exactly what happens with thermodynamic properties
Suppose you know
and you know . You could integrate with respect to :
Notice that the "constant" is actually a function of because you integrated with respect to .
Then you use the part to determine .
That's the same mathematical procedure you're seeing in this example.
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